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Blue hydrogen from crude oil gasification
The chemistry of gasification
The chemistry of gasification fits somewhere between combustion and pyrolysis. Combustion is a high temperature reaction in an excess of oxygen. It produces heat, carbon dioxide and steam. Pyrolysis is the high temperature decomposition of a hydrocarbon to form solid carbon in the absence of oxygen. It is used to produce coke from coal in steel making
mega-scale refinery petcoke gasification projects for the 2020s:
Today, one of the world’s largest gasification projects is at Saudi Aramco’s Jazan refinery in Saudi Arabia where more than a dozen gasifiers built by the Spanish Company Técnicas Reunidas will produce syngas from petcoke, a heavy refinery residue.
One of the drivers behind refinery residue gasification projects has been the IMO 2020 regulation which has increased the demand for low sulphur marine fuels. Furthermore, Petcoke has recently been banned in India for use as cheap feed to coal fired power plants due to its high sulphur content. Instead, gasifying it to produce syngas and hydrogen, which is used to desulphurise or hydrogenate fuels, can create value from the Petcoke.
At Jazan, the gasifiers will produce enough syngas to generate 4 GW of power and steam. The syngas is fired directly in gas turbines which produce 2,400 MW of electricity in an integrated gasification combined cycle (IGCC) power plant.
Gasification consumes vast quantities of oxygen to make hydrogen
Coal and petcoke have similar properties as gasification feedstocks. Both can be used to yield hydrogen for the refinery or for chemicals production. The Lu’an coal to chemicals project at Changzhi in China’s Shanxi province, is a large coal gasification project. Four gasification reactors have been constructed to supply syngas to a chemical complex and four large ASUs feed the gasifiers with oxygen. A methanol-based syngas purification plant sits downstream of the gasifiers.
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